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NEWS

2024-08-08

Featured as the Front Cover Art in Chem. Sci.

Our cover art was selected as Front cover. of Chemical Science. 

 

Link for the Cover Art:
https://pubs.rsc.org/en/content/articlelanding/2024/sc/d4sc90154a



2024-06-16

the 45th Workshop on Photochemistry for Young Researchers_Chair and Awarded

6月14日~16日に伊豆山研修センターで行われた第45回光化学若手の会に参加しました。
今回、関が世話人となって明治薬科大学の木村先生と京都大学の山内先生とともに、準備をしました。
関研からはM2の岡田君と斎藤君、M1の石川君と矢野君の4人が参加しました。
2日目にポスター発表を行い、矢野君が優秀ポスター発表賞を受賞しました(博士学生の受賞が多く、修士の受賞は他に1人のみ)。
準備や当日の運営など、大変でしたが無事に終われてよかったです。
学生のみんなは、炎天下の中、タクシー移動の誘導の大役をこなしてくれました。
全ての参加者にあらためて感謝いたします。


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RESEARCH

Our group develops stimuli-responsive molecular-based materials, such as crystals, liquid crystals, organogels and etc. We try to elucidate so far unknown responses of such materials and provide novel functionality of molecules.

Molecular-based materials exhibiting stimuli-responsivity

Molecular crystals or liquid crystals often show properties and functionality different from its individual molecule itself. This is caused by the neighboring molecules within the assembled materials which are connected through various intermolecular interactions. This indicates that the molecular-based materials can show properties/functionalities based on assembled states. Upon applying external stimulations to such materials, such as temperature change, photoirradiation and mechanical stimulations, the assembled states/molecular arrangements can change. As a result, these molecular-based materials exhibit various responses, i.e., property changes and mechanical movement.

Bridging the gap between macroscopic externals stimulation and microscopic molecular arrangement

We have reported that the molecular-based materials exhibiting emission color changes, electronic conductivity changes, and mechanical movements upon applying mechanical stimulation. These stimuli-responses are caused by the “macroscopic” mechanical force by means of a spatula or a pestle/mortar, which leading to changes in “macroscopic” molecular arrangements and patterns of intermolecular interactions. Our group tries to elucidate precise molecular arrangements within the crystals/liquid crystals to identify the effect of external stimulation, bridging the gap between macro- and microscopic information.

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Publications

2024

85. Benzodifuranone Crystals with Solid-State Emission Arising from the Introduction of Bulky Substituents,
T. Seki, T. Okada,
Chem. Eur. J., 2024, 30, 53, e202402622
DOI: 10.1002/chem.202402622.
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84. Preparation of intrinsically fragile bent crystals,
T. Seki, S. Kobayashi, R. Ishikawa, K. Yano, T. Matsuo, S. Hayashi,
Chem. Sci., 2024, 15, 12258–12263
DOI: 10.1039/d4sc02918f.
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83. (日本語) Mechanochromic aromatic hydrocarbons that bear one simple substituent,
T. Seki, K. Hattori,
RSC Adv., 2024, 14, 11, 7258–7262
DOI: 10.1039/d3ra08519h.
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Abstract

Sorry, this entry is only available in Japanese.

2023

82. (日本語) Functional Molecular Crystals from the Arylation of a Halogenoplatinum Complex: Stimuli-Responsiveness, Comproportionation, and π-Bridged Dimerization,
T. Seki, D. Korenaga,
Chem. Eur. J., 2023, 29, 62, e202302333
DOI: 10.1002/chem.202302333.
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Abstract

Sorry, this entry is only available in Japanese.

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