静岡大学 関朋宏 研究室

関朋宏 研究室

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Anisotropic strain release in a thermosalient crystal: Correlation between the microscopic orientation of molecular rearrangements and the macroscopic mechanical motion

Two gold N-heterocyclic carbene complexes show contrasting luminescent mechanochromism behavior with hypso- and bathochromic spectral shifts. The distinct emission shifts upon mechanical stimulation can be explained by the aggregate-to-monomer transformation and intensified intermolecular interactions, respectively.